“…Ti 3 C 2 T x MXene stands out as showing excellent mechanical properties and metallic electrical conductivity, surface functional groups (−O, −F, −OH), high thermal conductivity, and ion intercalation and thus has found numerous applications in various sensors. − However, the mechanical property, strength, and brittleness of MXene are relative low due to the sheet structure, and its tendency for restacking and relatively weak oxidation resistance remain challenges for practical utilization . Hybridization of MXene with various low-dimensional nanomaterials or polymers to form nanocomposites can be an effective strategy to overcome the limitations, as the low-dimensional nanomaterials can be the spacers to expand the MXene multilayers and promote the reversible intercalation reactions of charge carriers. − Aramid nanofibers (ANFs), a novel 1D nanomaterial, are considered one of the strongest chemical fibers, with high tensile strength (∼4 GPa), high tensile modulus (∼129 GPa), and good thermal stability. , Their excellent reinforcement abilities allow them to be high-performance polymer substrates, reinforcing phases, and also the “building blocks” in constructing advanced composites . Black phosphorus (BP) is an emerging 2D nanomaterial with puckered structure and exhibits high mobility, weak van der Waals interactions, good electrical conductivity, unique hinge structure, and reactive edge structure. , …”