Ti 3 C 2 T x , a novel two-dimensional material in the MXene family, was successfully prepared and applied as a saturable absorber (SA) for solid-state pulsed lasers at 2 µm. Pumped by a 792 nm fiber-coupled laser diode, a compact passively Q-switched Tm,Gd:CaF 2 laser with a Ti 3 C 2 T x -SA was demonstrated and the pulse laser performances were presented and discussed in detail. This is the first presentation of Ti 3 C 2 T x as a SA for solid-state pulsed laser generation near 2 µm.