2018
DOI: 10.1007/s12678-018-0455-5
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Silver/Nickel Oxide (Ag/NiO) Nanocomposites Produced Via a Citrate Sol-Gel Route as Electrocatalyst for the Oxygen Evolution Reaction (OER) in Alkaline Medium

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Cited by 34 publications
(31 citation statements)
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“…This value is even lower than that of the commercial IrO 2 catalyst (442 mV). For the Ag/rGO sample, a much bigger overpotential (730 mV) is needed, indicating a poor OER activity, and the fluctuation of the OER LSV polarization curve at 1.5–1.6 V should be ascribed to the oxidation of silver . Figure e shows the mass specific actives of different samples at overpotentials of 500 and 600 mV, respectively.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…This value is even lower than that of the commercial IrO 2 catalyst (442 mV). For the Ag/rGO sample, a much bigger overpotential (730 mV) is needed, indicating a poor OER activity, and the fluctuation of the OER LSV polarization curve at 1.5–1.6 V should be ascribed to the oxidation of silver . Figure e shows the mass specific actives of different samples at overpotentials of 500 and 600 mV, respectively.…”
Section: Resultsmentioning
confidence: 99%
“…For the Ag/ rGO sample, am uch bigger overpotential (730 mV) is needed, indicating ap oor OERa ctivity,a nd the fluctuation of the OER LSV polarization curve at 1.5-1.6 Vs hould be ascribed to the oxidation of silver. [22] Figure 4e shows the mass specific actives of different samples at overpotentials of 500 and 600 mV,r espectively.I tc an be seen that Co 3 O 4 /Ag@NrGO shows the highest mass specific activity among the four samples, which are 0.056 (h = 500 mV) and 0.087 mA mg À1 (h = 600 mV), respectively.W hereas,t he Ag/rGO sample shows the worst mass specific activity.F igure 4f shows the potentiald ifferences (DE)o f the four samples between E j = 10 and À3mAcm À2 ,a nd the smaller DE represents the betterb ifunctionality towards ORR and OER.I tc an be seen, among the four samples thatC o 3 O 4 / Ag@NrGO shows the smallest DE (0.93 V), which is also lower than those of similar catalysts recently reported in the literature (shown in Table 2). [23] In order to investigate the long-term stability of Co 3 O 4 / Ag@NrGO during the ORR, a4 0000 sc hronoamperometry (CA) test has been conducted at 0.4 V. The inset in Figure 5a shows the current retention curveso fC o 3 O 4 /Ag@NrGO and Pt/C catalysts during the CA tests.…”
Section: Resultsmentioning
confidence: 99%
“…The value at which the CV scan crossed the zero line gave the RHE‐value (0.91 V). All measurements were conducted at 25 °C [48]. trueEnormalinormalRnormalcnormalonormalrnormalrnormalenormalcnormaltnormalenormald=4ptEnormalanormalpnormalp-4ptnormalinormalRu trueEnormalRnormalHnormalE=normalE4pt()Vvs.Hg/HgO+0.914ptnormalV4pt()RHE …”
Section: Experimental Methodsmentioning
confidence: 99%
“…The value at which the CV scan crossed the zero line gave the RHEvalue (0.91 V). All measurements were conducted at 25°C [48].…”
Section: Electrochemical Characterisationmentioning
confidence: 99%
“…Different oxides have been used as catalysts in electrode preparation [16,17]. Oxides of molybdenum, either alone or accompanied by cobalt, have been widely studied in heterogeneous catalysis and recently in electrocatalysis [18].…”
Section: Introductionmentioning
confidence: 99%