We study the blackbody spectrum from slabs of three-dimensional metallodielectric photonic crystals consisting of gold nanoparticles using an ab initio multiple-scattering method. The spectra are calculated for different photonic-crystal slab thicknesses, particle radii and hosting materials.We find in particular that such crystals exhibit a broadband emission spectrum above a specific cutoff frequency with emissivity of about 90%. The studied photonic crystals can be used as efficient selective emitters and can therefore find application in thermophotovoltaics and sensing.
1The main feature of photonic crystals is the ability to tailor the photon density of states and this way control the spontaneous emission of light, aiming at the realization of new optoelectronic devices. In this context, there has been considerable effort to design and fabricate photonic crystals which allow for control of thermal emission of light, i.e. thermally driven spontaneous emission, promising applications in imaging, sensing and most importantly, in thermophotovoltaics (TPV). 1,2,3,4,5,6,7,8,9 Control of thermal emission can also be achieved by means of microstructured engineering on silicon 10,11,12,13 or metal surfaces. 14 Depending on the type of application, photonic crystals and structured surfaces can act as narrow-or wide-band, directional or isotropic thermal emitters. For example, in TPV applications 15 a quasi-monochromatic emission is preferable whilst in radiation cooling 16 a broad emission spectrum is desired. In this work we investigate the emission properties of three-dimensional metallodielectric photonic crystals consisting of gold nanoparticles. We find, in particular, that the emission spectrum of these crystals can be such that photons are emitted in all directions only when their energies lie above a specific cutoff frequency, with emissivity as large as 90%.Photonic crystals of spherical scatterers have been theoretically studied using multiple scattering theory 17,18 which is ideally suited for the calculation of the transmission, reflection and absorption coefficients of an electromagnetic (EM) wave incident on a composite slab consisting of a number of planes of non-overlapping particles with the same two-dimensional (2D) periodicity. For each plane of particles, the method calculates the full multipole expansion of the total multiply scattered wave field and deduces the corresponding transmission and reflection matrices in the plane-wave basis. The transmission and reflection matrices of the composite slab are evaluated from those of the constituent layers. Having calculated these matrices one can evaluate the transmittance T (ω, θ, φ), reflectance R(ω, θ, φ), and from those two, the absorbance A(ω, θ, φ) of the composite slab as functions of the incident photon energy ω and incident angles θ and φ. Transmittance and reflectance are defined as the ratio of the transmitted, respectively the reflected, energy flux to the energy flux associated with the incident wave. The method applies equally well...