Simple preparation of Ag-BTC-modified Co₃Mo₇O₂₄ mesoporous material for capacitance and H₂O₂-sensing performances

Abstract

Injecting polyoxometalates (POMs) clusters into the metal organic frameworks (MOFs) can not only provide more additional redox centers, but also solve the problems of easy agglomeration and low stability of...

Advancing biomedical applications of polyoxometalate-based metal–organic frameworks: from design to therapeutic potential

“…Cui et al proposed a method for grafted POMOF to detect H 2 O 2 by cyclic voltammetry and chronoamperometry. 38 The POMOF material synthesis method is to synthesise (AsW 12 @MOF) [(Ag 7 bpy 7 Cl 2 ){As(W V ) 2 (W VI ) 10 40 The POMOF material synthesis method was modified and synthesised by solid-phase self-assembly method with Co 3 Mo 7 O 24 @Ag-BTC-2, and the POM material was injected into MOFs. The detection mechanism is electrochemical catalysis of H 2 O 2 , and the response current is gradually enhanced with increasing H 2 O 2 concentration in electrochemical characterisation.…”

New pyrimidine-amide-tetrazole ligand derived polyoxometalate-based copper complexes as catalysts for sulfide-sulfoxide transformation and electrochemical sensors

“…The introduction of N-containing ligands into transition metal and POM systems to construct POMOCs is the main approach. 18–22 While N-containing ligands, such as pyridine derivatives and azole derivatives have been widely studied in recent years, 23,24 there are few reports on the construction of POMOCs based on pyrimidine derivatives. 25,26 At the same time, organic ligands containing amide bonds are considered to be one of the suitable research objects due to their rich N/O coordination sites among many derived ligands.…”

A host–guest compound formed by Cu3[P2W18O62] and HKUST-1 with capacitance and H2O2 sensing properties

“…Based on our previous study, [24][25][26][27][28][29] the host-guest Cu 3 [P 2 W 18 O 62 ]@HKUST-1 (HRBNU-7) compound was obtained by grinding. The morphology and structure of HRBNU-7 were analyzed, and the supercapacitor performance and H 2 O 2 sensing performance were tested, providing a strategy for the synthesis and application of POMOFs.…”