Industrial and academic
societies have been bothered
with the generation
and subsequent management of residues settled out from household bleach,
due to its corrosive properties. Therefore, the aim of this research
was to introduce a NaOH-impregnated calcium-based solid catalyst from
the aforementioned sediments for waste cooking oil transesterification.
To prepare the catalyst (RC-ITB), the wet impregnation technique was
followed and successfully characterized via X-ray diffraction (XRD),
X-ray fluorescence(XRF), differential scanning calorimetry (DSC),
Brunauer–Emmett–Teller (BET), Fourier transform infrared
(FT-IR), and scanning electron microscopy (SEM) methods. The study
findings suggested that RC-ITB has a BET surface area of 9.312 m2 g–1 and is largely made up of calcium with
its compound forms such as carbonates, hydroxides, and oxides. The
evaluation of pH values verified that RC-ITB is more alkaline (i.e.,
pH = 12.65) relative to its precursor RC (pH = 10.66), largely attributable
to OH impregnation. To study the catalytic performance, three numeric
factors with three levels of treatment were used, and their influences
were analyzed through a response surface approach. Accordingly, the
optimal yield of biodiesel was found to be 80.04% at a reaction temperature
of 61 ± 2 °C, catalyst weight of 6.33 wt %, and a molar
ratio of 23.94. Moreover, FTIR analysis verified that the glycerol
part of triglycerides had been replaced with a methoxyl unit. Also,
the fuel quality parameters of the FAME product were examined, including
density, kinematic viscosity, acid value, density, cetane number,
cloud point, saponification value, and pour point; all of these values
fall within the ASTM D6751-accepted limits. Thus, the findings showed
that the sediments of household bleach production could be a candidate
source to explore heterogeneous basic catalysts.