Simple synthesis of a hierarchical LiMn_0.8Fe_0.2PO₄/C cathode by investigation of iron sources for lithium-ion batteries

Abstract

A hierarchical porous LiMn0.8Fe0.2PO4/C (N-LMFP) was synthesized by a simple solid-state method beneficial for engineering applications. The fine particle and hierarchical porous structure enable a superior rate performance of the N-LMFP sample.

Surface Modification Engineering Enabling LiMnxFe1−xPO4 Cathode Against Aggressive Cathode Chemistries for Excellent Performance Lithium‐Ion Batteries

“…And the facile reaction of Mn 2 + with the electrolyte compounds the challenge of attaining outstanding electrochemical performance for the cathode of LIBs. [22][23][24] To overcome the above shortcomings of LMP, researchers have put forward the idea of replacing Mn with various other transition metals (Mg, Zn, Fe, etc.). This substitution is undertaken with the goal of producing composite materials known as LiMn x M 1À x PO 4 , with the intention of enhancing the electrochemical dynamics of the battery during both charging and discharging processes, thereby improving its overall electrochemical performance.…”

Improved Electrochemical Performance of LiMn0.6Fe0.4PO4 via Chitosan‐Derived Nitrogen‐Doped Carbon Coating

“…Addressing these challenges, the exploration of a LiMn x Fe 1‐x PO 4 (LMFP) solid solution, achieved by incorporating Mn 2+ with a similar radius to Fe 2+ , has gained global attention [12–13] . However, the increase in bandgap and congestion within LMFP necessitate improvements in electronic and ion conductivity [14] .…”

“…x PO 4 (LMFP) solid solution, achieved by incorporating Mn 2 + with a similar radius to Fe 2 + , has gained global attention. [12][13] However, the increase in bandgap and congestion within LMFP necessitate improvements in electronic and ion conductivity. [14] Furthermore, the intrinsic Jahn-Teller effect of Mn 2 + /3 + poses additional constraints on the reaction kinetics of LMFP cathode materials during rapid charging/discharging processes.…”