This article is concerned with formulation of three-dimensional thin film model for an antisurfactant solution and hence constructing unique global solution for a two-dimensional Riemann problem for the corresponding reduced hyperbolic form. We develop six geometrically different structures of the solution using generalized characteristic analysis method while relaxing the restriction that only one planar elementary wave is developed at the interface of each initial discontinuity. We analyze the interactions of classical and nonclassical waves in detail to construct the global solution of the corresponding 2-D Riemann problem. Further, we provide the expressions for strength, location, and propagation speed of delta shock wave at each interaction point. Moreover, we compare these solutions with the solutions of a one-dimensional rotated initial value problem and prove that our solutions are globally unique.