In capacitance-coupled voltage-sensing technology, the degree of coupling capacitance is affected by the sensing area, relative position deviation, and other factors, and thus the measurement coefficient is often difficult to determine accurately and presents greater implementation difficulties in actual deployment. This paper proposes a dynamic reconfiguration based on the measurement circuit topology of the voltage sensor adaptive calibration method in order to measure voltage sensor gain in the process of automatic measuring. Firstly, the basic principle of voltage measurement is introduced, and the self-calibration method is proposed, considering the influence of the sensing area and the relative position error on the change in the coupling capacitance. On this basis, the influence of calibration accuracy on sensor structure parameters is analyzed using network sensitivity analysis, and the parameter selection principle is given, according to which the selection criterion of parameter optimization is formulated to complete the sensor design. By analyzing the coupling effect of the three-phase measurement, the installation method of the sensing structure is proposed. An experimental platform is built to test the accuracy of the voltage measurement of the sensor under laboratory conditions. The experimental results show that the maximum relative error of the voltage measurement amplitude is 2.24%. In order to verify the feasibility of the sensor technology designed, the measurement models that integrate communication, acquisition, and processing are installed on both ends of the circuit breaker wire, and the voltage waveform generated during the circuit breaker closing process is recorded in real time. The experimental results show that the sensor technology can accurately record the voltage waveform of the signal to be measured, and the feasibility of its application in switchgear equipment signal measurement is preliminarily verified by the results.