The effect of reaction/regeneration cycles on some structural
characteristics of a NiMo/Al2O3
hydrotreatment catalyst has been studied. The first regeneration
produces increases in pore
volume, porosity, and specific area. Above 5% coke deposit,
various changes in such properties
appear. Mo and Ni relative XPS intensities depend on the
reaction/regeneration cycles Ni
exposure decreases with them, whereas Mo exposure follows the opposite
trend. The effect of
coke on metal dispersion seems to be almost negligible. Coke
concentration proved to be the
variable which really influenced coke composition (H/C), independently
of the history of the
catalyst. The equation relating both variables is
H/C = 0.4378 + 1.342
exp[(−C
c/S
e)/0.059]
where
C
c is the percentage coke concentration and
S
e the specific surface area.