The
present study investigates the impact and freezing behavior
of the droplets of surfactant solutions on non-wettable coatings at
very low temperatures of −10 to −30 °C. Our goal
is to elucidate the critical role of concentration, molecular weight,
and ionic nature of surfactants on these phenomena. To achieve this
goal, we used sodium dodecyl sulfate (anionic), hexadecyltrimethylammonium
bromide (cationic), and n-decanoyl-n-methylglucamine (nonionic) at four concentrations ranging from 0
to 2 × CMC (critical micelle concentration). We captured the
impact-freezing of the droplets on superhydrophobic alkyl ketene dimer
coatings using a high-speed camera at 5000 frames per second. The
results show that the ability of the droplets to spread and retract
on the coatings is a function of concentration, ionic nature, and
molecular weight of the surfactants, as well as the temperature-dependent
viscosity of the solutions. Additionally, surfactant-laden droplets
generally demonstrated an accelerated freezing compared to pure water.
This might be due to the fact that the presence of surfactants can
promote both heterogeneous ice nucleation from within the liquid and
a larger solid–liquid interfacial area by filling the air pockets
of the surface, leading to enhanced heat transfer. The behavior of
the cationic surfactant at certain concentrations was, however, an
exception leading to a freezing delay, for which a mechanism will
be proposed.