Natural gas processing involves the
removal of acidic gases, followed
by dehydration. The dehydration process is primarily carried out through
absorption in triethylene glycol (TEG). During the dehydration process,
volatile organic compounds (VOCs) including benzene, toluene, ethylbenzene,
and isomers of xylene together known as BTEX present in natural gas
are absorbed into the glycol solvent. During the thermal regeneration
process of TEG, a substantial amount of BTEX and VOCs are emitted
resulting in adverse environmental and health impacts, leading to
the need for strict regulations. Effective mitigation of emission
is essential for the natural gas industry. There are several process
parameters associated with major equipment that may impact BTEX emission.
Regulation of some of these parameters is found to have an adverse
impact on the dehydration process as well. In this work, a multi-objective
optimization is performed in order to find the optimal operating conditions
related to the process parameters to mitigate BTEX emission. It is
also essential to select the most important parameters from a larger
set so that a reliable analysis can be performed using the reduced
set of parameters. The analysis is performed using data-driven modeling
using machine-learning algorithms, followed by optimization with a
probabilistic technique. The least absolute shrinkage and selection
operator (lasso) method is used for variable selection; support vector
regression (SVR) is used for metamodeling; and a novel metaheuristic
optimization algorithm, efficient ant colony optimization (EACO),
is used for optimization. The surrogate or metamodel is generated
with data obtained from process simulation carried out using ProMax.
Using the lasso–SVR–EACO strategy, different optimized
sets of operating conditions that minimize the BTEX emission for a
stipulated dry gas water content, were obtained. The results show
that BTEX released from the dehydration process can be mitigated by
optimally choosing the TEG circulation rate, reboiler temperature,
stripping gas flow rate, and absorber pressure.