Fogging
on transparent surfaces such as goggles causes a series
of hazards to users. To fabricate antifogging and low-haze transparent
renewable polymer materials, intrinsic hydrophilicity with high water
adsorption capability of thermoplastic starch (TPS) had been adopted.
Strikingly, when benzoic acid (BA) was blended with thermoplastic
starch (TPS-BA), the haze of TPS-BA was only 7.8% when it suffered
the cold and warm method of antifogging measurement with 87% transmittance.
Simultaneously, TPS-BA achieved an 18 mm inhibition zone for Staphylococcus aureus. To reveal the antifogging
mechanism of TPS-BA films, the surficial and interior structure features
were evaluated by three-dimensional optical scanner, scanning electron
microscopy (SEM), contact angle testing, small-angle X-ray scattering
(SAXS), X-ray diffraction (XRD), temperature-dependent Fourier transform
infrared (FTIR), dynamic mechanical analysis (DMA), and so on. The
incorporation of BA resulted in the roughness (R
q), water contact angle (WCA), and crystallinity of the TPS-BA
film decreasing from 6.5 to 0.68 μm, 65.1 to 39.9°, and
13.6 to 6.3%, respectively. The amorphous matrix and smooth surface
reduced the scattered light, allowing the TPS-BA film to achieve low
haze performance and high transmittance. Importantly, the diversified
and weakened hydrogen bonds formed among starch, BA, and glycerol
could inhibit the formation of starch crystalline regions and allowed
hydroxyl groups to quickly bond with water. Thus, when TPS-BA is placed
in a high-humidity surrounding, an “expressway” is constructed
for water molecules diffusing into the TPS-BA matrix. This novel low-haze,
antifogging, sustainable, and facilely fabricated TPS with antibacterial
properties is a promising candidate in disposable medical goggles
to fight against COVID-19.