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Abstract 25Leveraging on the experience gained by designing and assembling a prototype experimental 26 apparatus reusing CO 2 to produce methane in a reaction with H 2 , we are developing an 27 alternative innovative cost effective and contaminant resistant synthetic strategy based on the 28 replacement of the solid phase catalysiswith a homogeneous gas phase processgoing through 29 the forming CO 2 2+ molecular dications. 30