2020
DOI: 10.1002/cite.202000068
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Simulation of Methanol and Urea Production from Catalytic Conversion of Steel Mill Gases

Abstract: The time‐dependent operation of methanol, ammonia, and urea production units embedded in a steel mill environment is analyzed with dynamic simulation models. From different process concepts and gas availability scenarios, a set of simulation cases is defined with blast furnace gas as carbon and coke oven gas as hydrogen source. Dynamic simulations indicate that significant CO2 reductions require large amounts of additional H2 from sustainable sources. From the results, global data such as carbon footprint or e… Show more

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Cited by 13 publications
(12 citation statements)
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“…The process-technology model focuses on the precise modeling of the methanol reactor and links this model to a dynamic process simulation of the network. In this case, the software COMSOL Multiphysics 5.5 was applied [27]. The detailed process simulation helps to understand the chemical processes and is also validated with experiments.…”
Section: Methodological Approachmentioning
confidence: 99%
“…The process-technology model focuses on the precise modeling of the methanol reactor and links this model to a dynamic process simulation of the network. In this case, the software COMSOL Multiphysics 5.5 was applied [27]. The detailed process simulation helps to understand the chemical processes and is also validated with experiments.…”
Section: Methodological Approachmentioning
confidence: 99%
“…Currently, further process concepts are intended to be implemented for product baskets as well as alternative CO 2 -containing sources from cement, limestone, waste incineration industries and steel production via direct reduction. Furthermore, already performed simulations [3] and modeling will be more deeply executed to determine dynamic design variables, i.e., design fields of the aggregates and plant controls, to support engineering design. This is necessary since previous work showed that the dynamic operation of the plants required in the network, depending on the scenario and operating concept, can place new demands on many components that cannot be represented by conventional design methods using operating points alone.…”
Section: Systemic Approach For the Implementation Of Cross-industrial...mentioning
confidence: 99%
“…The subsystems from the flow chart in Fig. 1 [20]. The PEM has a maximum load jump of ΔP max = 40 % max h -1 .…”
Section: Process Conceptmentioning
confidence: 99%
“…Schlüter and Hennig [19] described a simulation concept for synthesizing methanol from steel mill off-gases with hydrogen supply from water electrolysis. The following work by Schlüter and Geitner [20] points out the time-dependent significant influence of different gas usage scenarios and process concepts of the input gas carbon binding ratio (CBR) for methanol and urea production.…”
Section: Introductionmentioning
confidence: 99%