The postcombustion technology involved
the application of the deep
air-staged combustion technology to circulating fluidized bed (CFB)
combustion. To further develop its de-NO
x
potential, three kinds of fuel were adopted to investigate the conversion
of carbon and nitrogen along the postcombustion chamber (PCC) in a
0.15 MWth CFB test platform. By ultimate analysis of fly
ash and gas components analysis, it was found that the char content
in fly ash and CO in the gas phase gradually decreased along the PCC
and the flue gas pass. The majority of CO and char particles in fly
ash would burn out in the PCC. Similar to char and CO, the nitrogen
content in fly ash also gradually decreased along the PCC and the
flue gas pass. Although the fuel-N was gradually released into the
gas phase, the NO
x
concentration first
sharply increased and then slightly decreased instead of increasing
monotonically. In addition, the relationship between fuel-N conversion
and fuel characteristics was established. The results indicated that
the conversion rate of fuel-N in the furnace and in the PCC increased
with volatile content and fixed carbon content, respectively. This
phenomenon proved that the volatile nitrogen (volatile-N) and char
nitrogen (char-N) had different transformation tendencies in the postcombustion
technology. Moreover, the most likely conversion paths of fuel-N in
the postcombustion technology were proposed. Based on the above findings,
it was inferred that the NO
x
from the
combustion of coal with low volatile content and high fixed carbon
content would be higher in the postcombustion technology. The NO
x
emission experiment results agreed with
the above reference well.