This work established
a three-dimensional model of a chemical looping
system with multistage reactors coupled with hydrodynamics and chemical
reactions. The thermal characteristics in the chemical looping combustion
(CLC) system were simulated using coal as fuel and hematite as an
oxygen carrier (OC). Some significant aspects, including gas composition,
particle residence time, backmixing rate, wall erosion, carbon capture
rate, etc., were investigated in the simulation. Owing to the optimization
by adding baffles in the fuel reactor (FR), the gas conversion capacity
of the multistage FR was high, where the outlet CO2 concentration
was as high as 93.8% and the oxygen demand was as low as 3.8%. Through
tracing and analyzing the path of char particles, we found that the
residence time of most char particles was too short to be fully gasified.
The residual char will be entrained into the air reactor (AR), reducing
the CO2 capture rate, which is only 80.3%. In the simulation,
the wall erosion on the cyclone could be relieved by increasing the
height of the horizontal pipe. In addition, improving the structure
of the AR loop seal could control the residual char entrained by OC
particles to the AR, and the CO2 capture rate was increased
up to 90% in the multistage CLC reactor.