Rotary solid desiccant wheels are used as sensible and latent heat recovery wheels in the Desiccant-HVAC systems. The two major types of these wheels include enthalpy (total energy recovery) wheels which remove sensible heat and latent heat from process air and transfer them to regeneration air, and dehumidification wheels which transfer a significant amount of moisture (latent heat) at the same time minimizes heat transfer. In this work a set of novel design of hybrid rotary desiccant wheel constructed using a composite homogeneous mixture of solid desiccants (multiple types of silica gel and molecular sieves) are proposed. The transport phenomena taking place in the proposed set of novel design of hybrid rotary desiccant wheel are simulated numerically using an in house finite volume method based CFD code. The performances of these wheels are compared with conventional type of wheels made of molecular sieves and silica gel, respectively. The results show that the performance of these hybrid wheels are enhanced by up to 40 % by using these novel composite wheel designs.