Idealized mathematical models for multitubular packed-bed
reactors, based upon simplifying
assumptions concerning symmetry, regularity, and homogeneity of the
packing and the
intertubular space, are commonly used for analysis and design. In
reality, substantial deviations
from these assumptions occur and give rise to maldistributions, both
for the flow of reactants
through a packed tube and for the flow of a heat-transfer medium
through the intertubular
space. These maldistributions and methods of how to deal with them
in reactor design and
simulation are reviewed in this paper.The following areas are
covered: (i) porosity and flow
patterns inside tubes, (ii) heat and mass transfer inside tubes, (iii)
flow distribution over
individual tubes, and (iv) distribution of coolant flow over the
intertubular space.