Simultaneous Determination of Multiclass Pesticides and Antibiotics in Honey Samples Based on Ultra-High Performance Liquid Chromatography-Tandem Mass Spectrometry

Orso, Débora; Floriano, Luana; Ribeiro, Lucila C.; Bandeira, Nelson Miguel Grubel; Prestes, Osmar D.; Zanella, Renato

doi:10.1007/s12161-015-0339-8

Cited by 65 publications

(41 citation statements)

References 42 publications

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“…A comparison of the proposed method and other reported techniques [1,3,27,[29][30][31][32][33][34] for the determination of amide herbicides in solid matrices was summarized in Table 2. As mentioned before, fish sample is a fatty and protein-rich solid matrix.…”

Section: Comparison Of the Proposed Methods With Other Reported Technimentioning

confidence: 99%

Ultrasound-assisted extraction and solid-phase extraction for the simultaneous determination of five amide herbicides in fish samples by gas chromatography with electron capture detection

Bai

Zhang

et al. 2017

J. Sep. Sci.

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An efficient sample extraction and clean-up method was developed for simultaneous determination of five amide herbicides (alachlor, acetochlor, propisochlor, metazachlor, and butachlor) in fish samples. The protocol consisted of ultrasound-assisted solvent extraction and solid-phase extraction clean-up. In detail, aliquots of homogenized fish flesh were thoroughly mixed with 20 mL of n-hexane and then extracted with ultrasonication for 40 min. Each sample was centrifuged and the supernatant was collected for the subsequent clean-up. For the sample preparation, the above supernatant was processed with a C column with 3 mL of dichloromethane/n-hexane (1:1, v/v) as the eluant. Then the samples were analyzed by gas chromatography with electron capture detection. The correlation coefficients of the five calibration curves were 0.9976-0.9998 (n = 3). The limits of detection (S/N = 3, n = 11) and limits of quantification (S/N = 10, n = 11) were 0.19-0.42 and 0.63-1.39 μg/kg, respectively. The recoveries of this method were 71.2-92.6% with good precision (<4.7% relative standard deviations, n = 6). The developed method was successfully applied to monitor the five amide herbicides in fish samples collected from different cities.

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Section: Comparison Of the Proposed Methods With Other Reported Technimentioning

confidence: 99%

Ultrasound-assisted extraction and solid-phase extraction for the simultaneous determination of five amide herbicides in fish samples by gas chromatography with electron capture detection

Bai

Zhang

et al. 2017

J. Sep. Sci.

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“…When collecting pollen and nectar from flowers, bees transfer chemical contaminants to their beehives, with the result that they are detected in honey (Orso et al 2016;Tette et al 2016a;Barganska et al 2013). These chemical pollutans are grouped into three toxicity classes (low, medium, and high) Highly toxic insecticides (constituting the largest group of the compounds) are dangerous to pollinating organisms, even in sublethal doses .…”

Section: Introductionmentioning

confidence: 99%

Liquid Chromatographic MS/MS Analysis of a Large Group of Insecticides in Honey by Modified QuEChERS

2018

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The analytical tool for analysis of pesticide residues in honey must still be improved. Therefore, a sensitive, selective, rapid, and reliable analytical method for the analysis of pesticide residue belonging to 29 different classes at very low concentration levels was developed. Over 130 insecticides were extracted from the honey matrix using different amounts of sample, concentrations of the extraction solvent, and cleanup sorbents. Acceptable extraction recoveries accounting for matrix effect were obtained using the cleanup sorbent combination chitosan/aluminum oxide/C8 (200/200/200 mg) and 1% FA in ACN. Determinations were made by liquid chromatography-tandem mass spectrometry (LC-MS/MS). For most compounds, the recoveries range from 70 to 120%, with relative standard deviations < 20%. Linear correlation coefficients (r2) were higher than 0.99 at concentration levels of 0.001-0.100 mg kg−1. A positive matrix effect was observed for up to 95% of organophosphates and 43% of pyrethroids and a negative effect for 37% of neonicotinoids. This work showed that the presented method is convenient and reliable for quick monitoring of insecticides in honey samples.

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“…FM‐6‐1 was increased with the degradation of triflumizole, which was the only metabolite that consistently occurred higher than 10% total radioactive residues (percentage of total radioactivity at sampling time). Although previous studies have established methods of analysing boscalid and triflumizole residue in dried hops, avocado, honey, pepper, cabbage and cucumber, there have been no records so far regarding simultaneous determination of boscalid, triflumizole and FM‐6‐1 in the cucumber ecosystem using the rapid resolution liquid chromatography (LC)–triple quadrupole tandem mass spectrometry (MS/MS) technique. Hence, to develop an effective method for simultaneous multiresidue analysis of boscalid, triflumizole and FM‐6‐1 in cucumber is a hugely important part of food analytical chemistry.…”

Section: Introductionmentioning

confidence: 99%

Dissipation behaviour and dietary risk assessment of boscalid, triflumizole and its metabolite (FM‐6‐1) in open‐field cucumber based on QuEChERS using HPLC–MS/MS technique

Niu

2018

J Sci Food Agric

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Simultaneous Determination of Multiclass Pesticides and Antibiotics in Honey Samples Based on Ultra-High Performance Liquid Chromatography-Tandem Mass Spectrometry

Cited by 65 publications

References 42 publications

Ultrasound-assisted extraction and solid-phase extraction for the simultaneous determination of five amide herbicides in fish samples by gas chromatography with electron capture detection

Ultrasound-assisted extraction and solid-phase extraction for the simultaneous determination of five amide herbicides in fish samples by gas chromatography with electron capture detection

Liquid Chromatographic MS/MS Analysis of a Large Group of Insecticides in Honey by Modified QuEChERS

Dissipation behaviour and dietary risk assessment of boscalid, triflumizole and its metabolite (FM‐6‐1) in open‐field cucumber based on QuEChERS using HPLC–MS/MS technique

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