A new highly uorescent hybrid material (CD@Eu-MOF) was synthesized by encapsulating CD (Carbon Dots) prepared from citric acid and ethylenediamine on the basis of a metal-organic framework prepared from Eu 3+ and 1,2,4-benzenetricarboxylic acid. The prepared composite not only maintains the excellent uorescence properties of CD and Eu 3+ respectively, but also forms a dual-emission uorescence system, and the system has good stability in aqueous solution. It was further used as a novel uorescent probe for the detection of Fe 3+ , which can effectively exclude the interference of other metal ions from the detection, and the intensity ratio of I Eu /I CD of CD@Eu-MOF material has a good linear relationship with Fe 3+ in the range of 1-200 μM. In this study, computer vision and BP (Back Propagation) neural network were used to train and t the sample data, and it was veri ed that the actual uorescence color of CD has a good linear relationship with Fe 3+ concentration. In addition, the BP neural network also veri ed that the uorescence spectrum data of CD@Eu-MOF also has a good linear relationship with Fe 3+ concentration.This study provides a new method for the fabrication of ratio and colorimetric Fe 3+ uorescence sensors, and provides a feasible solution for the simple and visual detection of Fe 3+ in the environment.