2015
DOI: 10.1039/c5ra14360h
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Simultaneous electronic and ionic conduction in ionic liquid imbibed polyacetylene-like conjugated polymer films

Abstract: Electron and ion conducting polymer film prepared by hydroiodic acid catalyzed dehydration of poly(vinyl alcohol) and 1-propyl-3-methylimidazolium iodide blend.

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Cited by 15 publications
(34 citation statements)
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“…Synthesis of Polyacetylene Films : A 5 wt% solution of poly(vinyl alcohol) (PVA) in a solvent blend consisting of water and ethanol (4:1, volume ratio) was used for the preparation of precursor films . Hydriodic acid (47 wt%) was added dropwise to the PVA solution (1:1, molar ratio).…”
Section: Methodsmentioning
confidence: 99%
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“…Synthesis of Polyacetylene Films : A 5 wt% solution of poly(vinyl alcohol) (PVA) in a solvent blend consisting of water and ethanol (4:1, volume ratio) was used for the preparation of precursor films . Hydriodic acid (47 wt%) was added dropwise to the PVA solution (1:1, molar ratio).…”
Section: Methodsmentioning
confidence: 99%
“…Synthesis of Polyacetylene Films : A 5 wt% solution of poly(vinyl alcohol) (PVA) in a solvent blend consisting of water and ethanol (4:1, volume ratio) was used for the preparation of precursor fi lms. [ 54 ] Hydriodic acid (47 wt%) was added dropwise to the PVA solution (1:1, molar ratio). The precursor polymer solution was cast in a Tefl on mold, dried under dynamic vacuum at 60 °C for 12 h, and reacted at 200 °C for 1 h. The resulting fi lms were found to be about 100 μm thick.…”
Section: Synthesis Of Polymer Filmsmentioning
confidence: 99%
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“…), also in parallel with a serial ionic resistance ( R ion. ) and Warburg ion diffusion element ( W ) elements …”
Section: Resultsmentioning
confidence: 99%
“…At present, several different strategies are used to design and fabricate MIECs. They are: (1) mixing of conjugated polymers and polyelectrolytes [e.g., poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate)], (2) imbibing ionic fluids in conjugated polymer films, (3) incorporating ion conducting side chains on conjugated polymers, (4) ion‐doped or oxidized conjugated polymers, and (5) diblock copolymer with ion conducting and electronic conducting polymers as the constituent blocks [e.g., poly(3‐hexylthiophene)‐ b ‐poly(ethylene oxide) (P3HT‐ b ‐PEO)] . However, these methods do not afford separate and systematic control over the morphology and properties of the ionic and electronic conducting phases while keeping the overall morphology constant.…”
Section: Introductionmentioning
confidence: 99%