2015
DOI: 10.1002/elan.201400480
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Simultaneous Titration of Ternary Mixtures of Pb(II), Cd(II) and Cu(II) with Potentiometric Electronic Tongue Detection

Abstract: An automatic titration method is reported to resolve ternary mixtures of transition metals (Pb 2+ , Cd 2+ and Cu 2+ ) employing electronic tongue detection and a reduced number of pre-defined additions of EDTA titrant. Sensors used were PVC membrane selective electrodes with generic response to heavy-metals, plus an artificial neural network response model. Detection limits obtained were ca. 1 mg·L -1 for the three target ions and reproducibilities 3.0% for Pb 2+ , 4.1% for Cd 2+ and 5.2% for Cu 2+ . The syste… Show more

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Cited by 10 publications
(6 citation statements)
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“…Still, concerning the presence of heavy metals in soils, an automatic titration method was proposed employing an e-tongue integrated to an automatic microburette, used as an endpoint detection method in titration to resolve ternary mixtures of Pb 2+ , Cd 2+ , and Cu 2+ ions at mmol L −1 level. An ANN model afforded a high accuracy in the determination of Pb 2+ , with a reproducibility of 3.0% for Pb 2+ , 4.1% for Cd 2+ , and 5.2% for Cu 2+ [61].…”
Section: Computational Analysis Assisting E-tongues In the Detection mentioning
confidence: 99%
“…Still, concerning the presence of heavy metals in soils, an automatic titration method was proposed employing an e-tongue integrated to an automatic microburette, used as an endpoint detection method in titration to resolve ternary mixtures of Pb 2+ , Cd 2+ , and Cu 2+ ions at mmol L −1 level. An ANN model afforded a high accuracy in the determination of Pb 2+ , with a reproducibility of 3.0% for Pb 2+ , 4.1% for Cd 2+ , and 5.2% for Cu 2+ [61].…”
Section: Computational Analysis Assisting E-tongues In the Detection mentioning
confidence: 99%
“…Environmental monitoring is greatly hampered by the difficulty of heavy metal biosensing. The classification of soil, pollutant infiltration properties, organic content and macronutrient measurements, and soil contamination prediction have all been studied using ANNs (El Tabach et al, 2007;Wilson et al, 2015;Emamgholizadeh et al, 2017;De Souza et al, 2020;Teniou et al, 2021). Anagu et al, 2009 developed a sorption model for estimating heavy metal sorption from fundamental soil properties and assessing the dangers associated with their appearance.…”
Section: Environmental Monitoring Based On Artificial Neural Network ...mentioning
confidence: 99%
“…Three measurements per sensing unit were performed, with two independent replicates per sensor. Capacitance values were extracted from impedance data, and the whole spectra were statistically interpreted using Principal Components Analysis (PCA) [39].…”
Section: Detection Experimentsmentioning
confidence: 99%