Thermochromic (TC)
smart windows regulate building temperature
by adjusting their transmittance depending on ambient conditions.
Vanadium dioxide (VO2) is a leading TC material due to
its insulator-to-metal transition close to, but above, room temperature,
which modulates its transmittance in the near-infrared (NIR) region.
Implementing TC windows faces challenges such as lowering the phase
transition temperature of the TC material, ensuring high visible-light
transmittance, or enabling scalable fabrication. Multilayer structures
with buffer and antireflective (AR) layers address these challenges
by improving crystallinity and enhancing the transmittance properties.
We use ion-beam sputtering to deposit multilayer architectures of
the type AlN||VO2||AlN on quartz glass substrates. AlN
is chosen for its refractive index and protective qualities. The TC
properties of corresponding multilayer films with AlN as the buffer
and AR layer are explored, and structure–property relationships
are established. The results demonstrate promising advancements in
TC smart window technologies.