visualization and quantification of many flow properties, including scalar concentration and temperature measurements, and it has been long used in both low-and highspeed flows. PLIF imaging based on a variety of tracers has been considered through the literature [1]. Historically, acetone and 3-pentanone [2, 3] have been widely used for scalar and temperature imaging, and more recently, naphthalene [4,5], krypton [6], 1-methylnaphthalene [7], and anisole [8] have been utilized in a variety of applications.Toluene has been identified as a versatile candidate for PLIF studies owing to its large fluorescence quantum yield and strong temperature sensitivity [9][10][11][12][13]. Toluene PLIF has found many applications for the study of mixing, especially in internal combustion engine studies [10,12,[14][15][16][17] where the strong oxygen quenching [18] has been used to obtain a direct measurement of air/fuel ratio [1,12,19]. Some of the challenges (particularly related to pressure effects) on the use of toluene for fuel/air ratio measurements have also been identified [12,15,20,21]. The properties of oxygen quenching on fluorescence have also been exploited for a direct measure of oxygen concentration in both single-tracer [22] and dual-tracer [23] configurations. Furthermore, because of the relatively large fluorescence quantum yield, toluene PLIF has also been successfully used for high-framing-rate imaging configurations where laser pulse energies are typically limited [14,20,24].Toluene PLIF has proven to be a particularly robust approach for temperature measurements. Both singleand dual-band-detection schemes have been proposed [10, 13] and applied [16,[25][26][27][28][29]. Its use as a thermometry technique stems from the strong temperature dependence of the integrated fluorescence quantum yield and the temperature-induced red shift of the spectral fluorescence Abstract Single-excitation, dual-band-collection toluene planar laser-induced fluorescence (PLIF) is used to measure temperature and number density (or partial pressure) fields in non-uniform supersonic complex flows in the presence of mixing and compressibility. The study provides a quantitative evaluation of the technique in transverse jets in supersonic crossflow (JISCF). It is found that toluene PLIF is highly effective in visualizing the structure of supersonic flows and that temperature can be accurately inferred with acceptable signal-to-noise ratios (of order 30) even when mixing occurs. The technique was applied to several JISCFs that differ by jet fluid properties with resulting different structures. In the presence of compressibility and mixing, it is found that the PLIF signal is non-unique, a feature that is used to identify the mixing region of the transverse jet. Measurement errors due to camera registration errors have also been quantified. Because of the complexity of the flowfield, it is found that minute misalignment (<0.1 pixels) between the two PLIF images can introduce measurable errors on the order of tens of Kelvins and significa...