Single‐Atom and Dual‐Atom Electrocatalysts: Synthesis and Applications

Abstract

Distinguishing themselves from nanostructured catalysts, single‐atom catalysts (SACs) typically consist of positively charged single metal and coordination atoms without any metal‐metal bonds. Dual‐atom catalysts (DACs) have emerged as extended family members of SACs in recent years. Both SACs and DACs possess characteristics that combine both homogeneous and heterogeneous catalysis, offering advantages such as uniform active sites and adjustable interactions with ligands, while also inheriting the high stability and recyclability associated with heterogeneous catalyst systems. They offer numerous advantages and are extensively utilized in the field of electrocatalysis, so they have emerged as one of the most prominent material research platforms in the direction of electrocatalysis. This review provides a comprehensive review of SACs and DACs in the field of electrocatalysis: encompassing economic production, elucidating electrocatalytic reaction pathways and associated mechanisms, uncovering structure‐performance relationships, and addressing major challenges and opportunities within this domain. Our objective is to present novel ideas for developing advanced synthesis strategies, precisely controlling the microstructure of catalytic active sites, establishing accurate structure‐activity relationships, unraveling potential mechanisms underlying electrocatalytic reactions, identifying more efficient reaction paths, and enhancing overall performance in electrocatalytic reactions.