Single-Crystalline LiMn2O4 Nanotubes Synthesized Via Template-Engaged Reaction as Cathodes for High-Power Lithium Ion Batteries

Ding, Yuan‐Li; Xie, Jian; Cao, Gaoshao; Zhu, Tiejun; Yu, Haojie; Zhao, Xinbing

doi:10.1002/adfm.201001448

Cited by 339 publications

(210 citation statements)

References 57 publications

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“…Coupled with relatively low production costs and appreciable electrochemical performance at high discharge rates and elevated temperatures, LiMn2O4 is touted as a potential driver of future EV/HEV battery packs, notably against favourable LiFePO4 candidates [264]. Recent nanostructured morphologies of note include nanowires [265][266][267], nanorods [268][269][270][271][272], nanotubes [273], nanoparticles [269,[274][275][276] and ordered meso/porous electrodes [277,278]. Okubo et al [275] have demonstrated an important size-effect occurring in LiMn2O4 particles, confirming that bulk particle sizes are unable to achieve complete lithiation (up to Li2Mn2O4), due to their lower surface area.…”

Section: Limnxoymentioning

confidence: 99%

Evaluating the performance of nanostructured materials as lithium-ion battery electrodes

et al. 2013

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Access to the full text of the published version may require a subscription. Rights © Tsinghua University Press and Springer-Verlag Berlin ABSTRACTThe performance of the lithium-ion cell is heavily dependent on the ability of the host electrodes to accommodate and release Li + ions from the local structure. While the choice of electrode materials may define parameters such as cell potential and capacity, the process of intercalation may be physically limited by the rate of solid-state Li + diffusion. Increased diffusion rates in lithium-ion electrodes may be achieved through a reduction in the diffusion path, accomplished by a scaling of the respective electrode dimensions.In addition, some electrodes may undergo large volume changes associated with charging and discharging, the strain of which, may be better accommodated through nanostructuring. Failure of the host to accommodate such volume changes may lead to pulverisation of the local structure and a rapid loss of capacity. In this review article, we seek to highlight a number of significant gains in the development of nanostructured lithium-ion battery architectures (both anode and cathode), as drivers of potential next-generation electrochemical energy storage devices.

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Section: Limnxoymentioning

confidence: 99%

Evaluating the performance of nanostructured materials as lithium-ion battery electrodes

et al. 2013

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“…LiFePO 4 is hard to satisfy the requirements of large energy storage systems because of its small tap density and low discharge voltage. Spinel LiMn 2 O 4 is one of the most promising cathode material due to low cost, abundant resources, and nontoxicity [1,2]. However, the spinel LiMn 2 O 4 electrode suffers from a poor cycling behavior and severe capacity fading at elevated temperature [3,4].…”

Section: Introductionmentioning

confidence: 99%

Preparation of LiNi0.5Mn1.5O4 cathode materials by electrospinning

Zhong

Piao

Luo

et al. 2016

Ionics

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LiNi 0.5 Mn 1.5 O 4 cathode material was prepared by electrospinning using lithium hydroxide, manganese acetate, nickel acetate, acetic acid, ethanol, and poly(vinyl pyrrolidone) as raw materials. The effect of calcination temperature on the structure, morphology, and electrochemical properties was investigated. XRD results indicate that the LiNi 0.5 Mn 1.5 O 4 composite is well crystallized as a spinel structure at calcination temperature of 650°C for 3 h. SEM results reveal that this composite has a nanofiber shape with average size of about 300-500 nm. Electrochemical performance tests reveal that this composite shows the initial discharge capacity of 127.8 and 105 mAhg −1 at 0.1 and 3 C rates, respectively, and exhibits good cycling performance.

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“…Two pairs of oxidation current peaks and reduction current peaks for the cathode are distinct, revealing typical characteristics of two-stage reversible-phase transformation of the spinel LiMn 2 O 4 . Two pairs of separated redox peaks show that lithium ions are extracted and inserted from/into the spinel phase by a two-step process [45,46]. Figure 1a shows the cyclic voltammogram of a LiMn 2 O 4 particle in 0.7 M LiNTf 2 in MePrPyrNTf 2 +10 wt% GBL.…”

Section: Cyclic Voltammetrymentioning

confidence: 99%

Properties of LiMn2O4 cathode in electrolyte based on ionic liquid with and without gamma-butyrolactone

Swiderska‐Mocek

2013

J Solid State Electrochem

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LiMn 2 O 4 was examined as a cathode material for the lithium-ion battery, working together with a room temperature ionic liquid electrolyte, obtained by dissolution of solid lithium bis(trifluoromethanesulphonyl)imide (LiNTf 2 ) in liquid N-methyl-N-propylpyrrolidinium bis (trifluoromethanesulphonyl) imide (MePrPyrNTf 2 ) with and without gamma-butyrolactone (GBL). The Li/LiMn 2 O 4 cell was tested by cyclic voltammetry, galvanostatic charging/ discharging, and with impedance spectroscopy. In the cyclic voltammograms for these electrolytes pairs of oxidation current peaks and reduction current peaks for the cathode are distinct, revealing typical characteristics of two-stage reversible-phase transformation of the spinel. The LiMn 2 O 4 cathode showed good cyclability and Coulombic efficiency (126 mAh g −1 after 50 cycles) working together with 0.7 M LiNTf 2 in MePrPyrNTf 2 +10 wt%. GBL ionic liquid electrolyte. At the C/7and C/5 rates, the LiMn 2 O 4 showed stable capacities of 124 and 120 mAh g −1 , respectively. Scanning electron microscopy images of pristine electrodes and those taken after electrochemical cycling showed changes which may be interpreted as a result of solid electrolyte interphase formation. The 0.7 M LiNTf 2 in MePrPyrNTf 2 and 0.7 M LiNTf 2 in MePrPyrNTf 2 +10 wt%. GBL electrolytes have a greater thermal stability range (no peak is observed below 230°C).

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Single-Crystalline LiMn2O4 Nanotubes Synthesized Via Template-Engaged Reaction as Cathodes for High-Power Lithium Ion Batteries

Cited by 339 publications

References 57 publications

Evaluating the performance of nanostructured materials as lithium-ion battery electrodes

Evaluating the performance of nanostructured materials as lithium-ion battery electrodes

Preparation of LiNi0.5Mn1.5O4 cathode materials by electrospinning

Properties of LiMn2O4 cathode in electrolyte based on ionic liquid with and without gamma-butyrolactone

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