The Haiyang-2D altimetry mission of China is one of the first Low Earth Orbit (LEO) satellites that can receive new B1C/B2a signals from the BeiDou-3 Navigation Satellite System (BDS-3) for Precise Orbit Determination (POD). In this work, the achievable accuracy of the single-receiver ambiguity resolution for onboard LEO satellites is studied based on the real measurements of new BDS-3 frequencies. Under normal conditions, six BDS-3 satellites on average are visible. However, the multipath of the B1C/B2a code observations presents some patchy patterns that cause near-field variations with an amplitude of approximately 40 cm and deteriorate the ambiguity-fixed rate. By modeling those errors, for the B2a code, a remarkable reduction of 53% in the Root Mean Square (RMS) is achieved at high elevations, along with an increase of 8% in the ambiguity-fixed rates. Additionally, an analysis of the onboard antenna's phase center offsets reveals that when compared to the solutions with float ambiguities, the estimated values in the antenna’s Z direction in the solutions with fixed ambiguities are notably smaller. The independent validation of the resulting POD using satellite laser ranging at 16 selected high-performance stations shows that the residuals are reduced by a minimum of 15.4% for ambiguity-fixed solutions with an RMS consistency of approximately 2.2 cm. Furthermore, when compared to the DORIS-derived orbits, a 4.3 cm 3D RMS consistency is achieved for the BDS-3-derived orbits, and the along-track bias is reduced from 2.9 to 0.4 cm using ambiguity fixing.