tin (Sn) on silicon or silicon-on-insulator substrates provide a natural route for continued improvement of properties of modern state-of-the-art Si devices with expanding functionalities for mass production. These materials underpin devices with new and/or enhanced properties for applications in electronics, optoelectronics, thermoelectrics, spintronics, sensors, and quantum electronics based on spin qubits.Mobility of free carriers in conduction (electrons) or valance (holes) bands, along with a reasonably large energy bandgap, is one of the most important quality measures of any semiconductor material, determining its suitability for applications in a large variety of classical electronic, optoelectronic, and sensor devices, as well as for novel applications in emerging quantum devices. Higher mobility enables faster operation of a device at lower power consumption and thus leading to reduced Joule heat dissipation, which is essential for scaling and increasing the speed of current electronic devices. It is even more important for those devices and electronics, which work at cryogenic temperatures and are intended to control distributed registers of quantum processors. [2] Also, carrier mobility is the critical quality for quantum devices, often playing a key role toward new discoveries. [3][4][5] When one or more dimensions of a material are reduced sufficiently to the nanometer range, at a scale comparable to the de Broglie wavelength of the carriers, its properties become different from those of the bulk (3D) material. With reduction in size, novel electrical, mechanical, chemical, magnetic, thermal, optical, and other properties emerge. The resulting structure which could be either 2D, 1D, or 0D is then called a lowdimensional structure or system. Compared to conduction band electrons, holes in the valance band possess more complex energy structure. This leads to many special properties including a reduced hyperfine interaction with nuclear spins that is useful for enhanced spin coherence in quantum devices, large and controllable spin-orbit interaction (SOI) for fast and locally addressable spin-based qubits, controllable light-heavy hole interaction for the energy band and g* (effective g-factor)-factor engineering, etc. [6] Compared to electrons, all these complex hole properties can be considered as additional resources for engineering new devices based on hole spins, on SOI, and now on superior mobility. This explains the recent fast-growing interest in p-type (i.e., hole) semiconductor materials for fundamental research