Oxygen atom densities were measured in situ in a CO 2 glow discharge, at pressures between 0.2 and 5 Torr . Two measurement techniques were compared, namely optical emission actinometry (using Ar as the actinometer) and High-Resolution Two-photon Absorption Laser Induced Fluorescence (HR-TALIF) normalised to Xe, and were found to give consistent results. The variation of the atomic oxygen density with gas pressure shows two different regimes with a transition around 1 Torr. Measurements of the O atom loss frequency under plasma exposure showed that this behaviour is caused by a change in the O atom loss mechanisms, which are dominated by surface processes in our experimental conditions. The corresponding recombination probabilities on Pyrex γ O are found to vary with the gas temperature near the wall for a constant surface temperature, similarly to what has recently been obtained in pure O 2 . However, the measured values are more than two times lower than γ O obtained in a O 2 plasma in similar conditions. The O atom densities are also compared to the dissociation fraction of CO 2 determined by infra-red absorption. The obtained CO and O densities show different behaviour as a function of the energy input. The simultaneous measurement of gas temperature, electric field, O, CO and CO 2 densities and O atoms loss frequency in the same conditions provides an ideal set of constraints for validating CO 2 plasma kinetic models.