Single-step incorporation of oh groups into the monosubstituted dodecahydro-closo-dodecaborate(2-) anion derivatives [B12H11SCN]2−, [B12H11I]2−, and [B12H11OC(O)CH3]2−

Facile synthesis of novel NH2-MIL-53(Fe)/AgSCN heterojunction composites as a highly efficient photocatalyst for ciprofloxacin degradation and H2 production under visible-light irradiation

“…4a, the NMFA composites contained both the characteristics of AgSCN and NH 2 -MIL-53(Fe). Specifically, the vibrational bands located at 505, 707, 1069, and 2089 cm −1 represented the bending, symmetric stretching, bending overtones and asymmetric stretching vibrations of the SCN −1 group, 29 respectively. More precisely, the characteristic vibrational bands of 707 and 2089 cm −1 could be attributed to the S-C and C-N groups.…”