By deep level transient spectroscopy (DLTS), emission and capture behaviors have been explicitly investigated for a single electron trap in a Si-doped β-Ga2O3 epilayer. Trap characteristics including activation energy for emission (E
emi
= 0.8eV), capture cross-section of 6.40×10-15 cm2 and lambda-corrected trap concentration (NTa
) of 2.48×1013 cm-3 were revealed, together with non-emission region width (λ = 267.78nm). By isothermal DLTS, in addition to the impact of temperature, electric-field-enhanced trap emission kinetics were studied. When a relatively low electric field (E ≤ 1.81×105V/cm at 330K), emission kinetics of the trap was modeled to comply with phonon-assisted tunneling (PAT), whereas the emission process was regarded to be dominated by direct tunneling (DT) for a relatively high electric field (E ≥ 1.81×105V/cm at 330K). A thermal-enhanced capture process has also been revealed and quantitatively studied, where a capture barrier energy of 0.15eV was extracted.