1980
DOI: 10.1016/0022-2852(80)90096-x
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Single vibronic level fluorescence spectra of sulfur dioxide

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1980
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Cited by 42 publications
(20 citation statements)
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“…A microsecond lifetime is expected for the optically bright 1 B 1 levels accessed after singlephoton excitation. 15,17,18,22,23,32,[67][68][69][70][71][72] On longer time scales, electric dipole forbidden fluorescence has been observed to occur from the (Ã) 1 A 2 well 10, 12, 15, 32, 71 (bond angles close to 100…”
Section: Clements Band Excitation and Relaxation Pathwaysmentioning
confidence: 99%
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“…A microsecond lifetime is expected for the optically bright 1 B 1 levels accessed after singlephoton excitation. 15,17,18,22,23,32,[67][68][69][70][71][72] On longer time scales, electric dipole forbidden fluorescence has been observed to occur from the (Ã) 1 A 2 well 10, 12, 15, 32, 71 (bond angles close to 100…”
Section: Clements Band Excitation and Relaxation Pathwaysmentioning
confidence: 99%
“…At excitation energies between 4.03 and 4.28 eV, the pump pulses span two or more Clements bands, preparing different degrees of symmetric stretch and bending mode excitation in the initially excited vibrational states. 5,6,13,14,22 Specifically, the Clements C and D, F, and G and N, N , and O bands were excited with the 4.03 eV, 4.12 eV, and 4.28 eV pump photons, respectively. The electronic and vibrational nature of the excited state evolved in time during and following the excitation process.…”
Section: Clements Band Excitation and Relaxation Pathwaysmentioning
confidence: 99%
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“…The latter is intensively perturbed through Renner -Teller coupling with the ground state [7] and excitation into the B 1 B 1 state is associated with a weak underlying "quasi-continuum" in the absorption spectrum. The studies of single vibronic level fluorescence spectra by Shaw et al [8,9] gave credence to the explanation that the bulk of the emission is due to the B 1 B 1 levels spread among the A 1 A 2 levels.…”
Section: Introductionmentioning
confidence: 94%