In
recent years, chelating agents have garnered increasing attention
due to their unique capabilities in addressing challenges associated
with chemically enhanced oil recovery materials. Most previous studies
have primarily focused on examining the influence of chelating agents
on rock–fluid interactions. However, their effects on fluid–fluid
interactions, specifically on interfacial tension (IFT) characteristics
under various conditions, remain relatively unknown. This study investigates
the effect of crucial reservoir parameters on the performance of ethylenediaminetetraacetic
acid (EDTA) chelating agents in the IFT between crude oil and brine.
Furthermore, the study evaluated the impact of varying concentrations
of this agent on rock wettability alteration, zeta potential, and
spontaneous imbibition. The results illustrated that introducing EDTA
at high concentration into seawater (SW) solution reduced the IFT
by 85%. Additionally, while higher pH levels contributed to IFT reduction
due to increased hydroxyl ions, excessive salinity levels resulted
in elevated IFT. Raising the temperature from 30 to 75 °C further
decreased the IFT, changing the IFT for optimal EDTA concentration
from 20.43 to 2.56 mN/m (∼88% reduction). The changes in zeta
potential and contact angle measurements indicated that solutions
of 5 and 7 wt % EDTA shifted rock wettability from oil-wet to strongly
water-wet, resulting in the wettability alteration index of 1.01 and
1.02, respectively. Inductively coupled plasma analysis, on the other
hand, revealed substantial chelation of metal ions from both the solution
and rock when EDTA was added to the rock/SW system. This resulted
in a significant increase in Ca2+ ions and a decrease in
Mg2+ ions, attributed to the multi-ion exchange phenomenon.