In this study, we present the results of Young’s modulus and coefficient of friction (COF) of Ti–Ta surface alloys formed by electron-beam surface alloying by a scanning electron beam. Ta films were deposited on the top of Ti substrates, and the specimens were then electron-beam surface alloyed, where the beam power was varied from 750 to 1750 W. The structure of the samples was characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). Young’s modulus was studied by a nanoindentation test. The coefficient of friction was studied by a micromechanical wear experiment. It was found that at 750 W, the Ta film remained undissolved on the top of the Ti, and no alloyed zone was observed. By an increase in the beam power to 1250 and 1750 W, a distinguished alloyed zone is formed, where it is much thicker in the case of 1750 W. The structure of the obtained surface alloys is in the form of double-phase α’and β. In both surface alloys formed by a beam power of 1250 and 1750 W, respectively, Young’s modulus decreases about two times due to different reasons: in the case of alloying by 1250 W, the observed drop is attributed to the larger amount of the β phase, while at 1750 W is it due to the weaker binding forces between the atoms. The results obtained for the COF show that the formation of the Ti–Ta surface alloy on the top of Ti substrate leads to a decrease in the coefficient of friction, where the effect is more pronounced in the case of the formation of Ti–Ta surface alloys by a beam power of 1250 W.