2009
DOI: 10.1002/adfm.200801612
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Site‐Selective Self‐Assembly of Colloidal Photonic Crystals

Abstract: A scalable method for site‐selective, directed self‐assembly of colloidal opals on topologically patterned substrates is presented. Here, such substrate contains optical waveguides which couple to the colloidal crystal. The site‐selectivity is achieved by a capillary network, whereas the self‐assembly process is based on controlled solvent evaporation. In the deposition process, a suspension of colloidal microspheres is dispensed on the substrate and driven into the desired crystallization sites by capillary f… Show more

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Cited by 23 publications
(22 citation statements)
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“…Lithographic techniques have been used to pattern substrates (to direct colloidal crystallization) or to control and engineer point, line and planar defects 272. In order to have a total control on light propagation it is very important to be able to direct the growth of artificial opals on designed patterns and some approaches have been taken to fabricate photonic chips273, 274 combining micro‐fluidic techniques and soft lithography 275, 276. It is possible to define patterns on stamps to produce colloidal motives by nanoimprint 277.…”
Section: Further Processingmentioning
confidence: 99%
“…Lithographic techniques have been used to pattern substrates (to direct colloidal crystallization) or to control and engineer point, line and planar defects 272. In order to have a total control on light propagation it is very important to be able to direct the growth of artificial opals on designed patterns and some approaches have been taken to fabricate photonic chips273, 274 combining micro‐fluidic techniques and soft lithography 275, 276. It is possible to define patterns on stamps to produce colloidal motives by nanoimprint 277.…”
Section: Further Processingmentioning
confidence: 99%
“…Three‐dimensional (3D) PCs, which have enormous omnidirectional bandgaps, became an emerging field in the 1990s, since when various synthesis approaches have been proposed and demonstrated, such as self‐assembly,12–16 lithography,17–19 and direct laser writing 20–22. However, most of these methods bear inherent limitations that may hinder their practical deployment, for instance, complicated and costly micromanipulation techniques, the limited tunability of the stop band, and the difficulty of integration.…”
mentioning
confidence: 99%
“…The role of capillary filling in helping to order the deposited particles in the NP ink, and those that precipitate from the MOD ink, may also play a role, such as has been reported by Whitesides 24,25 for particles being packed into microchannels. Moreover, the control of evaporation imparted by the channels may well improve packing density, such as been reported for photonic crystal formation by Arpiainen et al 26 and Velev and Gupta. 27 Although it is worth remarking that the primary influence on resistance is the sintering regime, the initial packing of the crystals due to the confined geometry may well help to deliver improved performance.…”
Section: Discussionmentioning
confidence: 83%