Six-Membered Nitrogen Heterocycles from Xylaramide and Ribaramide

General syntheses of diterminal diaminodideoxyalditols and 1 -amino-1 -deoxyalditols from aldoses are described. Borane-THF reduction of -0-trimethylsilylaldaramides , followed by methanolic HC1 workup, leads to diaminodideoxyalditol dihydrochlorides . Similar treatment of 0-trimethylsilylaldonamides yields aminoalditol hydrochlorides. reaction sequence was used to synthesize six diaminoalditols and five monoaminoalditols .title aminoalditols and is independent of the chain length and stereochemistry of the starting aldose.

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Six-Membered Nitrogen Heterocycles from Xylaramide and Ribaramide

Cited by 2 publications

References 6 publications

ChemInform Abstract: SIX‐MEMBERED NITROGEN HETEROCYCLES FROM XYLARAMIDE AND RIBARAMIDE

ChemInform Abstract: SIX‐MEMBERED NITROGEN HETEROCYCLES FROM XYLARAMIDE AND RIBARAMIDE

A General Synthesis of Diterminal Diamnodideoxyalditols and 1-Amino-1-deoxyalditols Using Trimethylmsilyl Protecting Groups

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