Size-dependency of corrosion behavior for TiN nanostructure coatings deposited by the PACVD method

Elmkhah, Hassan; Mahboubi, F.; Abdollah-zadeh, A.; Ahangarani, Shahrokh; Raoufi, M.; Mahdipoor, M.S.

doi:10.1016/j.matlet.2012.04.154

Cited by 15 publications

(6 citation statements)

References 11 publications

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“…According to the analysis using Xpert software, it was found that the coating has an NaCl structure (B1 type) that crystallizes in the face centered cubic structure with Miller index (111), (200), (220), and (311). Since chromium (Cr) is in the position of titanium (Ti) as a substitute element, the structure of TiCrN coating is similar to the structure of TiN, like our previous work 21 . Also, using the Williamson‐Hall method, 22 the crystallite size of TiCrN nanostructured coating was calculated and was obtained in the range of 15 nm.…”

Section: Resultsmentioning

confidence: 79%

“…Since chromium (Cr) is in the position of titanium (Ti) as a substitute element, the structure of TiCrN coating is similar to the structure of TiN, like our previous work. 21 Also, using the Williamson-Hall method, 22 the crystallite size of TiCrN nanostructured coating was calculated and was obtained in the range of 15 nm.…”

Section: Morphology and Microstructure Analysis Of The Samplesmentioning

confidence: 99%

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The effect of substrate surface integrity on the surface properties of TiCrN coating applied via the CAE‐PVD method

Elmkhah

Mohammadi

Molaei

et al. 2022

Int J Applied Ceramic Tech

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This study aims to investigate how the predeposition machining processes such as magnetic grinding, turning machining, and wire electrical discharge machining can influence the surface properties including electrochemical and tribological behavior of TiCrN nanostructured coating applied on Mo40 steel substrate. A physical vapor deposition technique using cathodic arc evaporation was used to apply the coating. The crystallographic phases and the microstructure of the coating were studied by X-ray diffraction and scanning electron microscope, respectively. Rockwell-C, electrochemical impedance spectroscopy and potentiodynamic polarization, and pin-on-disk wear tests were employed to evaluate the adhesion strength, corrosion behavior, and tribological property of specimens, respectively. The electrochemical results after 24 h of exposure to 3.5 wt% NaCl solution showed that TiCrN coating pretreated with a turning process with polarization resistance of about 3525.32 Ω.cm 2 had the best corrosion resistance among all specimens. This was because of the improvement of the smoothness, surface quality, and adhesion after the turning process. On the other, the friction coefficient of the grounded sample is less than that of other ones. This is probably due to its higher adhesion strength and higher surface smoothness.

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Section: Resultsmentioning

confidence: 79%

Section: Morphology and Microstructure Analysis Of The Samplesmentioning

confidence: 99%

The effect of substrate surface integrity on the surface properties of TiCrN coating applied via the CAE‐PVD method

Elmkhah

Mohammadi

Molaei

et al. 2022

Int J Applied Ceramic Tech

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“…Researchers [51][52][53] studied effects of surface characteristics and the duty cycle on the corrosion behavior TiN films. When duty cycles increased, rougher surfaces with large size of grain was created.…”

Section: +*mentioning

confidence: 99%

A Review on Titanium Nitride and Titanium Carbide Single and Multilayer Coatings Deposited by Plasma Assisted Chemical Vapor Deposition

Azadi

Rouhaghadam

Ahangarani

2016

IJE

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In this paper, we reviewed researches about the titanium nitride (TiN) and titanium carbide (TiC) single and multilayer coatings. These coatings were deposited by the plasma assisted chemical vapor deposition (PACVD) technique. Plasma-based technologies are used for the processing of thin films and coatings for different applications such as automobile and aerospace parts, computer disc drives, food industry and surgical/medical instruments. We describe the state of the performance of different coating systems and thin film architectures in PACVD suitable for industrial-scale or laboratory applications. Mechanical properties of coatings such as wear resistance, hardness and the scratch resistance, structural characteristics, physical and chemical properties like coatings adhesion into different substrates, wetting behavior and corrosion resistance were studied. Thus, this paper represents a source of information for those who want to familiarize with the status of knowledge in the area of materials science of functional coatings, in particular TiN/TiC coatings that was deposited by a new Plasma-based technologies.

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“…In addition, TiN coatings have found extensive industrial applications, such as coatings on mandrels, drawing dies, cutting tools, molds, gears, and bearings [15,16], as they offer high hardness, wear, and corrosion resistance [17,18]; also, good thermal and electrical conductivities should be noted [19]. The TiN coating has been deposited on steels by various methods such as chemical vapor deposition (CVD) [7], combination of plasma nitriding and plasmaenhanced CVD [13], physical vapor deposition (PVD) [16], plasma-assisted chemical vapor deposition (PACVD) [20], and the duplex treatment method of the tufftriding followed by the pack titanium coating [14]. Wear-resistant TiN coatings have been investigated in different applied loads (up to 20 N [21-23] and 75 N [24]).…”

Section: Introductionmentioning

confidence: 99%

Influence of Treatment Sequence on Tribological Performance of Duplex Surface-Treated AISI 1045 Steel

Haftlang

Habibolahzadeh

2019

Acta Metall. Sin. (Engl. Lett.)

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The surface of AISI 1045 steel specimens was modified via two duplex surface treatments of (i) titanium diffusion coating followed by plasma nitriding (Ti-PN) and (ii) plasma nitriding followed by titanium diffusion coating (PN-Ti). A comparative study on the microstructure and wear properties of the fabricated TiN coatings was conducted. A scanning electron microscope equipped with energy-dispersive X-ray spectroscopy, X-ray diffractometer (XRD), and pin-on-disk wear test was utilized to evaluate the microstructures, phases, and wear properties of the coatings. XRD patterns of duplex-treated specimens illustrated that the modified layer consisted of nitride and carbo-nitride phases such as TiN and TiC 0.7 N 0.3 . The results also showed that Ti-PN treatment led to a low friction coefficient and the lowest wear factors, as compared with the PN-Ti treatment. Oxidation and mild fatigue fracture wear were found to be the main wear mechanism of the Ti-PN coating. The wear mechanism in the PN-Ti specimen involved a higher oxidative wear regime followed by plastic deformation wear regimes.

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Size-dependency of corrosion behavior for TiN nanostructure coatings deposited by the PACVD method

Cited by 15 publications

References 11 publications

The effect of substrate surface integrity on the surface properties of TiCrN coating applied via the CAE‐PVD method

The effect of substrate surface integrity on the surface properties of TiCrN coating applied via the CAE‐PVD method

A Review on Titanium Nitride and Titanium Carbide Single and Multilayer Coatings Deposited by Plasma Assisted Chemical Vapor Deposition

Influence of Treatment Sequence on Tribological Performance of Duplex Surface-Treated AISI 1045 Steel

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