Segregation is a widely occurring undesirable phenomenon in industries that store, handle and process particulate materials. Size-segregation induced by the percolation mechanism is observed in several important processes that negatively impacts the product quality and mixing. To quantify sizesegregation, a constitutive model based on simultaneous convective and diffusive demixing was developed and validated. The primary segregation shear cell (PSSC) was used to measure the fundamental parameters and validate the convective-diffusive segregation model. Glass beads of size