A new structural
isomer of nonasilane, 2,2,4,4-tetrasilylpentasilane or (H3Si)3SiSiH2Si(SiH3)3,
is formed in disproportionational condensation of neopentasilane.
This reaction can be catalyzed by a freshly cleaned borosilicate surface,
and the catalyzed reaction can have over 85% selectivity for this
branched nonasilane near 100 °C. A synthetic method has been
developed from this catalytic reaction for making 98 wt % 2,2,4,4-tetrasilylpentasilane.
The high-purity 2,2,4,4-tetrasilylpentasilane has a workable shelf
life in 316 stainless steel containers.