2022
DOI: 10.1002/ange.202213074
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Skeleton‐Reorganizing Coupling Reactions of Cycloheptatriene and Cycloalkenones with Amines

Abstract: Skeletal reorganization reactions have emerged as an intriguing tool for converting readily available compounds into complicated molecules inaccessible by traditional methods. Herein, we report a unique skeleton-reorganizing coupling reaction of cycloheptatriene and cycloalkenones with amines. In the presence of Rh/acid catalysis, cycloheptatriene can selectively couple with anilines to deliver fused 1,2dihydroquinoline products. Mechanistic studies indicate that the retro-Mannich type ring-opening and subsequ… Show more

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