We have obtained absolute spectrophotometry of the Kitt Peak night sky at a variety of azimuths and zenith angles. Our zenith measurements confirm the finding of Pilachowski et al. that Kitt Peak is still a dark site, as we find (B) = 22.8 mag/arc sec 2 and (V) = 21.9 mag/arc sec 2 on 1988 February 18, a night of fairly low solar activity. (A year later the sky was appreciably brighter; this increase correlates well with solar activity as measured from the 10-cm flux.) The "pseudocontinuum" encountered by spectroscopists is about 0.02-0.05 mag/arc sec 2 darker in B and 0.2-0.3 mag/arc sec 2 darker in V than the broad-band measures. The major line contributor to the B band is Hg, while the dominant source of contamination to the V-band measures are atmospheric lines, most notably O IX5577. Using fluxed observations of street lamps we find that the relative contribution to light pollution in the yellow-red (5000 Á-6500 Á) is 10% Hg, 30% LPS, and 60% HPS. The sky brightness increases a few tenths going from the zenith to a zenith distance of 60°, but the contribution of light pollution remains small. No significant azimuthal effects are seen : The sky is as dark toward Phoenix or Tucson as toward anywhere else, at least for zenith distances of 60° or less.Comparison with earlier measurements of the Kitt Peak sky brightness suggests that there has been no significant increase in light pollution at Kitt Peak from the mid-1960s to the late 1980s, a fact which we attribute to the stringent lighting ordinances adopted by the state.