CoCrMoSi alloys microstructure is affected by processing and their properties have been associated with the high volume fraction of Laves phase. However, not much has been reported on the effect of structure refinement and morphology on the properties of these alloys. This paper evaluates a CoCrMoSi alloy processed by centrifugal casting and Plasma Transferred Arc (PTA) hardfacing, aiming to understand the correlation between microstructure and properties at room temperature in the as-processed condition and following exposure at 600 °C. Characterization was carried out using scanning electron microscopy, X-ray diffraction, hardness and wear tests. The cooling rates associated with each of the processing techniques used account for the developed microstructures and associated hardness, a 626 HV 0,5 cast alloy and 649 HV 0,5 deposited alloy, the former exhibiting a coarser microstructure. Wear behavior was determined by the dispersion of solid solution areas in the microstructure and as a consequence temperature exposure aggravated the poorer wear resistance of the cast alloy. The finer phase dispersion formed in coatings overlapped the deleterious effects of dilution and account for the stable wear behavior after temperature exposure.