process requires deposition of consistent, uniform layers with a repeatable thickness distribution across multiple material classes. Different manufacturing methods such as spin or dip coating, [10] lithography, [11] doctor blading, [12] chemical vapor deposition, [13] and others have been used to fabricate thin-film devices. However, most of these methods are limited by substrate planarity, high temperatures, harsh chemistries, or the dissolution of previous layers by non-orthogonal solvents. [14] Furthermore, in certain situations, it is desirable to deposit a customized pattern or to selectively place components on an existing device structure without disturbing it. To address the challenges noted above, we examine an additive manufacturing (AM) approach and use it to realize vertically stacked, thin-film devices using multiple materials. AM technology in principle enables material deposition on nonplanar surfaces, by direct addition of material on existing topographies, without requiring cleanroom facilities and the use of masking steps more commonly used with lithography, and less material waste. Inkjet printing has been studied extensively for the creation of multimaterial, thin-film devices with demonstrated transistors [15-17] and optical sensors. [18] The thermal or piezo-driven excitation [19] used to deposit materials in a liquid phase in inkjet printing limits the achievable spatial resolution to larger than 20 µm. Furthermore, high viscosity inks (>50 cP) necessary for certain applications cannot be printed using inkjet technology. [20] Electrohydrodynamic jet (e-jet) printing is a solution-based fabrication technique enabling thin-film fabrication and patterning without the planarity restrictions of lithography and other subtractive processes. Compared to inkjet technology, e-jet printing has a much higher spatial resolution (0.05-30 µm), comparable to the resolution of lithographic processes, [20,21] while also providing a high degree of freedom in creating customized patterns. Complex structures can be fabricated with high controllability and precision in desired locations from the micro-to nanoscale. E-jet is also capable of depositing a wide range of fluid viscosities from 10 0-10 5 cP, several orders of magnitude larger than that of inkjet printing. [19] This further enables