Vehicle charging power supply is widely used because of its small size and portability. Aiming at the problems of slow dynamic response, subharmonic, oscillation and limited soft-switching range of phase-shifted full-bridge DC/DC converter, the paper proposed a modified PSFB converter by introducing clamp diodes at the primary side of the transformer to suppress voltage oscillation of the transformer’s secondary side. Also, digital peak current phase-shifting control and slope compensation are introduced to avoid subharmonic oscillation. Dynamic dead-time control technology introduced adjust the dead-time in different load ranges through the dead-time adjustment subroutine. Finally, an experimental platform of on-board charging phase-shifted full-bridge DC/DC converter is established. The experimental results show that the power supply eliminates subharmonic oscillation, achieves a wide range of soft-switching, improves the dynamic performance and antiinterference ability of the system, and optimizes the power efficiency.