The rise of wearable technologies has transformed how we interact with the world around us. This chapter explores the exciting potential of Artificial Intelligence (AI) and Machine Learning (ML) to further enhance wearables for education and teaching. By integrating AI and ML, wearable devices can evolve from simple data collectors to intelligent assistants that personalize learning, improve student engagement, and empower educators. We will delve into the core concepts of AI and ML, their role in wearable technology, and how they can be harnessed to create a more dynamic and effective learning environment. This chapter will explore specific applications of AI-powered wearables in education, analyze the benefits for both teachers and students, and address potential challenges and considerations for responsible implementation.