Smart
materials are a kind of functional materials which can sense
and response to environmental conditions or stimuli from optical,
electrical, magnetic mechanical, thermal, and chemical signals, etc.
Patterning of smart materials is the key to achieving large-scale
arrays of functional devices. Over the last decades, printing methods
including inkjet printing, template-assisted printing, and 3D printing
are extensively investigated and utilized in fabricating intelligent
micro/nano devices, as printing strategies allow for constructing
multidimensional and multimaterial architectures. Great strides in
printable smart materials are opening new possibilities for functional
devices to better serve human beings, such as wearable sensors, integrated
optoelectronics, artificial neurons, and so on. However, there are
still many challenges and drawbacks that need to be overcome in order
to achieve the controllable modulation between smart materials and
device performance. In this review, we give an overview on printable
smart materials, printing strategies, and applications of printed
functional devices. In addition, the advantages in actual practices
of printing smart materials-based devices are discussed, and the current
limitations and future opportunities are proposed. This review aims
to summarize the recent progress and provide reference for novel smart
materials and printing strategies as well as applications of intelligent
devices.