Sn-based deep eutectic solvents assisted synthesis of Sn and SnO2 supported hexagonal boron nitrides for adsorptive desulfurization

Li, Hongping; Zhang, Jinrui; Yi, Jianjian; Luo, Jing; Zhu, Siwen; Sun, Linghao; Xiong, Jun; Zhu, Wenshuai

doi:10.1016/j.cherd.2019.01.025

Cited by 23 publications

(5 citation statements)

References 48 publications

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“…DESs have been considered for the development of 2D nanomaterials such as graphene (GRA), for exfoliation of GRA layers, , for functionalization, or for improving materials performance such as lubrication . Additional systems formed by DESs and other 2D nanomaterials have been scarcely studied in the literature, and thus although some applications have been reported for the preparation of materials based on boron nitride (BN) or MoS 2 (MOS) 2D nanosheets, studies on other 2D materials such as silicene (SIL) or germanene (GER) are absent. The understanding of interfacial properties for DES + 2D materials systems is of great relevance for materials development, in particular considering that DESs have been probed to develop exfoliation of 2D materials and thus nanoscopic characterization is required.…”

Section: Introductionmentioning

confidence: 99%

Deep Eutectic Solvent Reline at 2D Nanomaterial Interfaces

Rozas

Aparício

2020

J. Phys. Chem. B

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The behavior of reline (choline chloride mixed with urea at a 1-to-2 mole ratio) deep eutectic solvent at the interfaces of 2D nanomaterials was studied by using molecular simulation methods. Graphene, boron nitride, silicene, germanene, and molybdenum disulfide were studied for considering the most relevant features of available 2D nanomaterials. The reline–nanomaterial interactions were analyzed, and the mechanism of reline adsorption with the properties at the interfaces was studied. Likewise, the behavior of the deep eutectic solvent upon confinement between parallel nanosheets was considered as a model of properties when placed in slit nanopores. The results provide a nanoscopic vision of the adsorption and confinement of reline regarding 2D nanomaterials, thus advancing the development of new materials based on deep eutectics.

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Section: Introductionmentioning

confidence: 99%

Deep Eutectic Solvent Reline at 2D Nanomaterial Interfaces

Rozas

Aparício

2020

J. Phys. Chem. B

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“…As a result, the creation of MOFs based on DESs as a green medium has given an excellent environment for the adsorption and capture of harmful gases throughout the union. Some of the most significant developments pertaining to this matter have been brought to your attention in Table 1 [51][52][53][54][55][56][57].…”

Section: Des-based Metal Organic Framework As a More Suitable Separatormentioning

confidence: 99%

Recent Achievements in Microporous Metal-Organic Frameworks Based on Ionic Liquids/ Deep Eutectic Solvents for Efficient Removal of Toxic Gases and VOCs

Rahmdel Delcheh

2023

PPS

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In recent years, micro-porous metal-organic frameworks, often known as MOFs, have received a great deal of interest owing to the remarkable gas storage and separation characteristics that they possess. This literature review investigates the progressive concepts surrounding the integration of Metal-Organic Frameworks (MOFs) with Ionic Liquids (ILs) and Deep Eutectic Solvents (DESs) for the purpose of the effective capture of Volatile Organic Compounds (VOCs). This study provides a full overview of the achievements made in this area by discussing the synergistic effects and increased performance gained via the combination of MOFs with ILs and DESs. These effects were accomplished through the combination of MOFs with ILs and DESs. In addition, the difficulties and potential benefits of the future that are related to this forward-thinking attitude are discussed.

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“…The process has the disadvantage of taking too much time for conversion of DBT. Li et al 109 synthesized Sn-based deep eutectic solvents (DESs) with urea and introduced them into h-BN as metal sources as well as reaction solvents. The as-prepared adsorbent was used for adsorptive desulfurization of DBT in comparison to commercial BN and showed higher adsorption capacity than the commercial BN.…”

Section: Desulfurization Of Fuelmentioning

confidence: 99%

Perspectives on Advances in the Catalytic Desulfurization and Denitrogenation of Transportation Fuel Oils Using Graphitic Carbon Nitride and Boron Nitride

et al. 2022

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Expulsion of sulfur-containing compounds as well as nitrogen-containing compounds present in fuel oils is critical because it can cause numerous environmental problems and catalyst deactivation. Because of the limitations of the other catalysts and adsorbents used for desulfurization, a new type of carbon material, i.e., graphitic carbon nitride (g-C3N4), has emerged. It is similar in morphology to graphene having a two-dimensional structure and possessing a band gap of 2.7 eV and is an attractive catalyst attributed to its intriguing characteristics like high intrinsic photoresponsiveness and photoabsorption, semiconductive properties, and better stability. An ample amount of literature has been documented on g-C3N4 applied for the desulfurization and denitrogenation of fuel oils. Due to the analogy of boron with carbon materials, boron nitrides (BN) are also important. In materials chemistry, hexagonal BN (h-BN), often termed as “white graphene”, among the different phases of BN, is highly regarded due to adaptation of diverse morphologies such as nanotubes and nanosheets. BN has been recommended as an emerging and efficacious 2D material in catalysis because it possesses oxidative resistance, chemically inertness, a sp2-bonded layered structure, wide band gap, and higher thermal stability and conductivity. This review systematically encompasses the important reports documented on the applications of g-C3N4 and BNs in fuel oil processing including the synthesis, various properties, and fascinating experimental findings. Later on, key suggestions are put forward for future research directions and new technologies applying g-C3N4 and BN for the processing of transportation fuels. This review could act as a concentrated platform, as a quick access source and great degree of convenience, giving time effective routes for researchers to reported results and designs of novel and efficacious catalysts for the commercialization of desulfurization and denitrogenation technologies.

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Sn-based deep eutectic solvents assisted synthesis of Sn and SnO2 supported hexagonal boron nitrides for adsorptive desulfurization

Cited by 23 publications

References 48 publications

Deep Eutectic Solvent Reline at 2D Nanomaterial Interfaces

Deep Eutectic Solvent Reline at 2D Nanomaterial Interfaces

Recent Achievements in Microporous Metal-Organic Frameworks Based on Ionic Liquids/ Deep Eutectic Solvents for Efficient Removal of Toxic Gases and VOCs

Perspectives on Advances in the Catalytic Desulfurization and Denitrogenation of Transportation Fuel Oils Using Graphitic Carbon Nitride and Boron Nitride

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