Hyperspectral satellite missions, such as PRISMA of the Italian Space Agency (ASI), have opened up new research opportunities. Using PRISMA data in land cover classification has yet to be fully explored, and it is the main focus of this paper. Historically, the main purposes of remote sensing have been to identify land cover types, to detect changes, and to determine the vegetation status of forest canopies or agricultural crops. The ability to achieve these goals can be improved by increasing spectral resolution. At the same time, improved AI algorithms open up new classification possibilities. This paper compares three supervised classification techniques for agricultural crop recognition using PRISMA data: random forest (RF), artificial neural network (ANN), and convolutional neural network (CNN). The study was carried out over an area of 900 km2 in the province of Caserta, Italy. The PRISMA HDF5 file, pre-processed by the ASI at the reflectance level (L2d), was converted to GeoTiff using a custom Python script to facilitate its management in Qgis. The Qgis plugin AVHYAS was used for classification tests. The results show that CNN gives better results in terms of overall accuracy (0.973), K coefficient (0.968), and F1 score (0.842).