2015
DOI: 10.1002/aoc.3267
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SnS and SnS2thin films deposited using a spin‐coating technique from intramolecularly coordinated organotin sulfides

Abstract: Synthesis and applications of organotin(II) sulfide ({2,6‐(Me2NCH2)2C6H3}Sn)2(μ‐S) (1), organotin(II) thiophenolate {2,6‐(Me2NCH2)2C6H3}Sn(SPh) (2) and organotin(IV) heptasulfide {2,6‐(Me2NCH2)2C6H3}2Sn2S7 (3) as potential single‐source precursors (SSPs) for the deposition of SnS or SnS2 thin films using a spin‐coating method are reported. Compounds 1, 2 and 3 differ either by tin oxidation state or by Sn:S ratio (Sn:S = 2:1 in 1, 1:1 in 2 and 2:7 in 3). It is shown that compound 1 is not a suitable SSP for th… Show more

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Cited by 15 publications
(4 citation statements)
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“…[40] When Se was used as oxidizing agent, a longer reaction time led to organotin(IV) selenide 49, containing the Sn-Se-Sn moiety and two terminal Sn=Se bonds. [41] The formation of analogous compounds were evidenced in the case of sulphur and tellurium, the organotin(IV) polysulfide 48, [40,43] its formation explained through a sulphide intermediate and tellurium, derivative 50 [42] , as shown in Scheme 9. Compound 50 was revealed to be unstable, decomposing to 52, while in the presence of moisture gave the stannaoxane 53.…”
Section: Reactivity Of Stannylenesmentioning
confidence: 94%
“…[40] When Se was used as oxidizing agent, a longer reaction time led to organotin(IV) selenide 49, containing the Sn-Se-Sn moiety and two terminal Sn=Se bonds. [41] The formation of analogous compounds were evidenced in the case of sulphur and tellurium, the organotin(IV) polysulfide 48, [40,43] its formation explained through a sulphide intermediate and tellurium, derivative 50 [42] , as shown in Scheme 9. Compound 50 was revealed to be unstable, decomposing to 52, while in the presence of moisture gave the stannaoxane 53.…”
Section: Reactivity Of Stannylenesmentioning
confidence: 94%
“…In most cases these sulfides are a result of reactivity studies performed on the corresponding organotin(IV) derivatives [11][12][13][14] and only rarely are used themselves in reactions. 16,17 We report here on the synthesis, characterization and crystal structure of some new homobimetallic triorganotin(IV) species with C,N imine -pendant arm ligands, i.e. [ (3), and the reactivity of 2 towards ZnCl 2 and ZnSO 4 .…”
Section: Introduction *mentioning
confidence: 99%
“…1 H and13 C resonances were assigned using 2D NMR experiments (COSY, HMQC and HMBC). The NMR spectra were processed using the MestReNova software 17. Mass spectra were recorded on a Thermo Scientific LTQ Orbitrap XL mass spectrometer equipped with a standard ESI/APCI source.…”
mentioning
confidence: 99%
“…[17][18][19][20][21] Up to now, most of the reported SnS 2 nanosheets are synthesized via exfoliation from bulk crystals, [22] chemical vapor deposition (CVD), [17,23,24] hydrothermal methods, [14] and spin coating techniques. [25] The most common methods are exfoliation and CVD. However, the size of layered SnS 2 obtained by exfoliation is usually limited because the thickness and size are difficult to control in this way.…”
Section: Introductionmentioning
confidence: 99%